You should have no problems if you have purchased your flight to Cambodia before you depart UK and it takes place less than 30 days after your arrival. While it is technically possible that without the Cambodia trip you could be denied boarding, experience suggests that it is highly unlikely. With the Cambodia trip it's straightforward and, after all, you are only looking to stay 42 nights or thereabouts. You would not need to visit immigration to obtain an extension, that you would get when you fly in from Cambodia, or even if you return overland.